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Battery, Battery Materials, Emerging Industry

 <2022> All-Solid-State Battery Technology Trend and Market Outlook (~2030)


 With the issues related to the stability and energy density of LiB continuously emerging in the industry, there are growing interests in developing next-generation batteries to address those issues. Among them, the all-solid-state battery has been attracting the biggest attention from the industry players in terms of stability and development readiness.

 

The all-solid-state battery can be categorized into three types: sulfide-based, oxide-based, and polymer-based. Each type has different advantages/disadvantages and pending issues. This report describes the advantages/disadvantages and issues related to each type as well as the details of their manufacturing processes. Furthermore, this report explores the major developments and achievements made by each battery maker and offers a market outlook for each type till 2030.

 

This report draws market estimates from comprehensive research on the level of technology development, requirements by OEMs and mass production targets of all-solid-state battery makers. The market analysis provided in this report is categorized into battery maker types, companies, and applications.

 

All of the above are provided in 10 chapters of which brief indexes are as stated in the following table of contents.

 

To provide a deeper insight, the 2022 report adds the SNE Insight chapter which deals with the challenges facing different electrolytes and tries to guide directions for their improvement. The chapter also investigates Semi Solid/Hybrid batteries and the mass production time and targets of different battery makers. The report is all the more meaningful as it offers a more detailed market outlook than the 2021 edition, based on the current status and future plans of all-solid-state battery developers.

 

 

 

Table of Contents

 

1. Introduction

 

     1.1 History of Battery Development

 

        1.1.1 History of Ancient Battery Development

 

        1.1.2 Manganese Battery (Leclanché cell)

 

        1.1.3 Alkaline cell

 

        1.1.4 Lead-acid battery

 

        1.1.5 Ni-Cd battery

 

        1.1.6 Ni-MH battery

 

        1.1.7 Lithium-ion battery

 

     1.2  Challenges with Lithium-Ion Battery

 

        1.2.1 Safety

 

        1.2.2 Energy Density

 

 

2. All-Solid-State Battery

 

     2.1  Advantages of All-Solid-State Battery

 

        2.1.1 Increase of Energy Density

 

        2.1.2 Availability in Application of New Active Materials

 

        2.1.3 Low Activation Energy

 

2.2  Manufacturing Process of All-Solid-State Battery

 

        2.2.1 Manufacturing of Electrolyte Layers

 

        2.2.2 Production of Anode and Cathode Composite Layers

 

        2.2.3 Cell Assembly

 

     2.3  Solid Electrolyte

 

        2.3.1 History of Solid Electrolyte Development

 

        2.3.2 Operation Mechanism of Solid Electrolyte

 

        2.3.3 Classification of Solid Electrolyte

 

     2.4 Influences of All-Solid-State Battery on Existing SCMs

 

 

3. Sulfide-Based Electrolyte

 

     3.1  Types of Sulfide-Based Electrolyte

 

        3.1.1 Thio-LISICON-based

 

        3.1.2 Binary sulfide-based

 

        3.1.3 Argyrodite-based

 

        3.1.4 Others: Li7P2S8I

 

     3.2  Synthesizing Methods for Sulfide-Based Electrolyte

 

        3.2.1 Solid-phase Synthesis

 

        3.2.2 Liquid-phase Synthesis

 

        3.2.3 Wet-chemical Synthesis

 

3.3  Synthesizing Methods for Core Raw Materials

 

        3.3.1 Core Raw Materials: Li2S

 

        3.3.2 Synthesis of Starting Materials

 

        3.3.3 Starting Material: Li metal

 

        3.3.4 Starting Material: Li2SO4

 

        3.3.5 Starting Material: Li2CO3

 

        3.3.6 Starting Material: LiOH

 

        3.3.7 Starting Material: Li-R

 

 

4. Oxide-Based Electrolyte

 

     4.1  Types of Oxide-Based Electrolyte

 

        4.1.1 Perovskite-based

 

        4.1.2 Garnet-based

 

        4.1.3 NASICON-based

 

        4.1.4 Li1+xAlxGe2-x(PO4)3 (LAGP)

 

        4.1.5 Others: Li2.9PO3.3N0.46 (LiPON)

 

     4.2  Synthesizing Methods for Oxide-Based Electrolyte

 

        4.2.1 Solid-phase Synthesis

 

        4.2.2 Solid-phase Synthesis

 

 

5. Polymer-Based Electrolyte

 

     5.1  Types of Polymer-Based Electrolyte

 

        5.1.1 PEO-based Electrolyte

 

        5.1.2 Polymer/Ceramic Composite

 

     5.2  Synthesizing Methods for Polymer-Based Electrolyte

 

        5.2.1 Blending method - PEO-based Electrolyte

 

        5.2.2 Blending method – Polymer/Ceramic Composite

 

 

6. All-Solid-State Battery R&D Trend

 

     6.1  Problems of All-Solid-State Battery

 

     6.2  All-Solid-State Battery R&D Trend

 

        6.2.1 Enhancement of Li metal stability

 

        6.2.2 Improvement of Electrode Binding Capacity

 

        6.2.3 Improvement of Pole Plate Manufacturing Process

 

     6.3  Sulfide-Based Electrolyte R&D Trend

 

        6.3.1 Improvement of Interfacial Stability of Solid Electrolyte/Electrode

 

        6.3.2 Improvement of Particle Segregation

 

        6.3.3 Suppression of Void Generation

 

        6.3.4 Improvement of Solid Electrolyte Performance

 

6.4  Oxide-Based Electrolyte R&D Trend

 

        6.4.1 Improvement of Solid Electrolyte/Electrode Contact

 

        6.4.2 Improvement of Solid Electrolyte Performance

 

     6.5  Polymer-Based Electrolyte R&D Trend

 

        6.5.1 Enhancement of Self-standing Characteristics of Electrolyte Layers

 

        6.5.2 Suppression of Li Dendrite Formation

 

 

7. Trend of All-Solid-State Battery Patents

 

     7.1 Outline of All-Solid-State Battery Patents

 

     7.2 Polymer-type Major Patents

 

     7.3  Inorganic, Organic/Polymer Hybrid Major Patens

 

     7.4  All-Solid-State Battery Patents – Raw Materials

 

     7.5  All-Solid-State Battery Patents – Battery Application

 

7.6  Core Patents by All-Solid-State Battery Material

 

 

 8. Current Status of ASB Developers

 

     8.1  In Asia

 

        8.1.1 Samsung Electronics

 

        8.1.2 Korea Institute of Industrial Technology

 

        8.1.3 LG Chem

 

        8.1.4 SK Innovation

 

8.1.5 Hyundai Motors

 

        8.1.6 Seven King Energy

 

        8.1.7 Toyota

 

        8.1.8 Hitachi Zosen

 

        8.1.9 TDK

 

        8.1.10 Ohara

 

        8.1.11 Murata

 

        8.1.12 Idemitsu Kosan

 

        8.1.13 APB

 

        8.1.14 FDK

 

        8.1.15 NGK SPARK PLUG

 

        8.1.16 Taiyo Yuden

 

        8.1.17 CATL

 

        8.1.18 Prologium

 

        8.1.19 Ganfeng Lithium

 

8.1.20 TDL

 

8.1.21 Coslight

 

8.1.22 Welion New Energy

 

8.1.23 BYD

 

8.1.24 Daejoo Electronic Materials

 

8.1.25 ISU Chemical

 

8.1.26 CIS

 

8.1.27 Hannong Hawseong

 

     8.2  In Europe

 

        8.2.1 Ilika

 

        8.2.2 Blue Solutions

 

        8.2.3 IMEC

 

8.2.4 Embatt

 

8.2.5 Innolith

 

8.2.6 Saft

 

8.3  In North America

 

       8.3.1 Solid Power

 

       8.3.2 Solid Energy Systems

 

       8.3.3 24M

 

       8.3.4 Hydro Québec

 

       8.3.5 Sakti3

 

       8.3.6 SEEO

 

       8.3.7 Brightvolt

 

       8.3.8 Ionic Materials

 

       8.3.9 TeraWatt

 

8.3.10 QuantumScape

 

8.3.11 Infinite Power Solution

 

8.3.12 Prieto

 

8.3.13 Factorial

 

8.3.14 Amprius

 

8.3.15 EoCell

 

8.3.16 Cymbet

 

8.3.17 Johnson energy storage

 

 

 

     8.4 Current Status of Joint Partnership for All-Solid-State Battery Development

 

     8.5 Status of Supporting Agencies by Region

 

        8.5.1  Global Cooperation Through Inter-national Government Funding

 

        8.5.1  Major Agencies in Asia

 

        8.5.2  Major Agencies in Europe

 

        8.5.3  Major Agencies in North America

 

8.6 Support Programs by Region

 

8.6.1  Japan

 

8.6.2  Europe

 

 

 

9. SNE Insight

 

     9.1 Drawbacks of Electrolyte by Type (Large-area Battery)

 

     9.2 Challenges and Development Direction for Different Electrolytes

 

     9.3 Various Types of Batteries (Hybrid/Semi Solid)

 

     9.4 Time of All-Solid-State Battery Mass Production by Companies

 

     9.5 Current Status and Future Direction of All-solid-state Battery Anode/Cathode

 

     9.6 Competition Amongst All-Solid-State Battery Types (Oxide/Sulfide/Polymer)

 

     9.7 Various Applications of All-Solid-State Battery

 

     9.8 Images of All-Solid-State Battery Production Facilities

 

 

 

10. All-Solid-State Battery Market Outlook

 

     10.1 Overview

 

     10.2 Market Outlook